There was also some discussion in bubo's log,
here.
In that discussion (link above), bubo mentions Lupine and Mila as sources of HID lights, and there are links to those manufacturers.
Honestly, though, I recommend you find a bunch of people with headlamps and talk to them. I'm thinking Jukola (or Tiomila if you can't wait that long).
I would love to see an English-language article, website, or post that compares headlamps and headlamp technologies (LED/Halogen/HID, NiCad, NiHM, Lithium). Maybe someone planning to go to Tiomila or Jukola could plan to walk around, gather information, and write about it. Some user reviews and objective tests would be great.
The lack of information might be an indication that 10W/20W halogen headlamps are a commodity, i.e., that the performance is so similar that you just need to buy one and you'll be competitive. With the new technologies, HID and LED and Lithium batteries, maybe that is changing.
I've seen one 5W LED headlamp (J-J's homebrew hatlamp) and the 5W is pretty impressive for moving through the woods, but maybe not as good as other lamps for finding controls. From what I've been reading, the 5W LED Luxeon is quite complicated to use correctly---A considerable amount of heatsinking and temperature monitoring is necessary to protect it from damage. It would be neat to see what 4 of these together (20W) would do. Prices are pretty high for these right now. 3W LEDs for flashlights seem to be sprouting up everywhere. An array of 3W LEDs might be promising.
I'm playing with some lithium-ion battery packs (the kind that have been exploding in laptops recently), and they have some weird characteristics. For example, it's bad to charge them up and leave them charged for months and months because it causes a permanent reduction in capacity. Surprisingly, it's okay to leave them in the discharged state for months and months, and although there is some evidence of reduced capacity, it's minor compared to the damage done if you store them fully charged. Also, it's vital to have a device to prevent using the battery below a certain voltage. Apparently the best thing to do with these is to cycle them regularly. I now run my iPod and cell phone down a lot more than I used to because of this---I don't keep the charge high. I know these have less weight than NiMH batteries, but I'm not sure they're better. It might not be worth the extra hassle. Maybe in a few years they'll be ready.