Celestrak has a preliminary orbit for tonight's starlink L26 launch (6:52 PM EDT). No predicts at heavens-above yet, but I plotted the track and made a .kml for the first orbit after launch, which should be visible from Moncton (note times on the map are EDT - watch for the pass starting at 9:40 PM ADT tonight).
Interesting orbit - its different than the usual elliptical initial starlink orbits. This one is nearly circular at the full operation altitude of ~570 km. This probably has to do with the rideshare payloads on this launch that may not have their own propulsion. The high altitude is the reason for the large magenta 10-deg elevation circle in the map here. Celestrak says the payload deploy will be at 8:32 PM EDT, right before our overhead pass. We might be able to see both the starlink stack and 2nd stage moving apart as they go overhead, although they'll still be very close together at that point. The late payload separation a full orbit after launch is also unusual. Should be a very high pass in Moncton (maybe 60 deg elevation in the NW) and pretty dark there already.
You should be able to see a similar pass in Truckee 3 hrs later. At that point the 2nd stage and starlink stack should be well separated - by tens of seconds. The starlink stack should have spread a little so will look like a very short line, while the falcon-9 second stage will just be a single dot.
Pass map and .kml for the pass over the NE:
starlink_L26_pass_5_15_2021.pngstarlink_L26_pass_5_15_2021.kml